The 48-year-old retired full-lower back will appear for Bull in the Barne United in Shrewsbury, western England, after the team received a charity "Dream Transfer" raffle on eBay in January.
Carlos is set to be involved as the team face fellow Shrewsbury and District Sunday League aspect Harlescott Rangers in a pleasant.
The Brazilian, who received the World Cup in 2002, most recently had a brief spell in India with Delhi Dynamos in 2015.
When it turned into announced in January that he could be turning out for Bull inside the Barne for one recreation, Carlos stated in a announcement: "I'm excited to play for Bull within the Barne in Shrewsbury, harking back to after I nearly signed for Birmingham City in the 90s, which could be very nearby.
"I've heard that the group's been down a number of gamers this season so right here's hoping my education is sufficient to help them up their game and bring what Bull within the Barne's lovers want to peer."
Bull within the Barne supervisor and goalkeeper Ed Speller stated: "Roberto Carlos is one of these legends who's stimulated so many younger gamers' love of the game.
"My jaw surely dropped while we discovered out Bull inside the Barne received the Dream Transfer and he's going to be playing along the group in Shrewsbury.
"It should be a proper chuckle for him to come see what we're product of, with a few disturbing unfastened-kicks and optimistically no dodgy tackles."
Money raised from the raffle has long gone to Football Beyond Borders, a charity that facilitates deprived younger human beings.